Product and Company Identification

(Page 1 may be used as an emergency safety sheet) Trade name: Low Halogen PVC Compound 135300 Chemical abstract no.: 9002-86-2 Chemical family: Polyvinyl Chloride with additives NIOSH no.: KU9625000 Chemical name: Polyvinyl chloride Synonyms: PVC Compound  

Composition

UN no.: Not clas Hazardous components: Polyvinyl Chloride, Antimony Trioxide R Phrases: R37  

Hazards Identification

Hard Grade PVC Compound 135300 is a pelletised granule and is either natural or black in colour. The compound has been designed for use as a low halogen PVC compound on Power Cables and conforms to SABS 1411 Part 2. The compound is very stable in its natural form and the normal precautionary measures should be taken when any contact is made with the material or in case of a fire. Eye effects: Fumes generated during processing may cause irritation. Health effects – skin: None, but avoid prolonged contact. Health effects – ingestion: Harmful as compounds contain lead stabilisers and antimony trioxide. Health effects – inhalation: Fumes generated during processing of PVC compound may cause irritation. Carcinogenicity: Not known. Mutagenicity: Not known. Neurotoxicity: Not known.  

First Aid Measures

Product in eye: Flush eyes with clean water. Medical attention may be necessary if irritation persists. Product on skin: Wash with soap and water. For hot product, flush the affected area with cold water to dissipate heat. Do not remove material from the skin. Get prompt medical attention. Product ingested: Wash out mouth and give plenty of water to drink. Seek medical advice. Product inhaled: Remove from exposure to fresh air. Seek medical advice.  

Fire Fighting Measures

Extinguishing media: CO2, Dry Chemical, Fog or Regular Foam may be used. Special hazards: The product is nonflammable and nonexplosive under normal conditions of use. When forced to burn, the major gaseous products are carbon monoxide, carbon dioxide, hydrogen chloride and water. Flame retardant additives ensure that the minimum quantity of hydrogen chloride is released. Protective clothing: An approved positive pressure self-contained apparatus must be worn.  

Accidental Release Measures

Personal precautions: Pellets may cause slippage on hard surfaces. Environmental precautions: No data is available on the adverse effects of this product on the environment. Small spills: Sweep up and discard in waste containers (recycle if possible). Large spills: May be disposed of by landfill as per local regulations.  

Handling and Storage

Suitable material: Keep stainless steel container tightly closed in a well ventilated place. Handling/storage precautions: Avoid contact with skin and eyes. Keep away from heat and sources of ignition.  

Exposure Controls/Personal Protection

Engineering control measures: Ventilation requirements – local exhaust. Personal protection – respiratory: Use approved dust respirators. Personal protection – hand: Minimise contact with product. Wear gloves. Personal protection – eye: Wear safety glasses with side shields, goggles or a face shield for protection against dust. Personal protection – skin: Minimise contact with product. Wear gloves and/or suitable long sleeved clothing. Other protection:  

Physical and Chemical Properties

Appearance: Pellets or Granules Odour: Faint soap like pH: Not applicable Boiling point: Not applicable Melting point: > 150ºC Flash point: > 450ºC Flammability: N/A Vapour pressure: N/A Density: 1.4 – 1.6 Solubility – water: Insoluble Solubility – solvent: Miscible in Cyclohexanone, Tetrahydofuran  

Stability and Reactivity

Conditions to avoid: Polyvinyl chloride is stable under normal conditions. Incompatible materials: Polyvinyl chloride is incompatible with strong oxidising agents like sulphuric acid (>90%) and nitric acid (>50%). Strong inorganic acids will attack the polymer at temperatures > 60ºC. Halogens like bromine and fluorine attack Polyvinyl chloride at room temperature and can result in violent reactions. Hazardous decomposition products: Thermal decomposition can result in the release of toxic vapours of hydrogen chloride, carbon monoxide and carbon dioxide.  

Toxicological Information

Acute toxicity: High concentrations of dust may irritate the upper respiratory tract. Vapour released during hot processing may cause respiratory irritation. Skin and eye contact: Repeated skin contact can cause irritation and abrasion. Direct eye contact can range from irritation to abrasion. Chronic toxicity: Chronic inhalation of dusts can cause pulmonary damage, blood effects and abnormal liver function. Carcinogenicity: Polyvinyl chloride is a questionable carcinogen with experimental tumorigenic data. Mutagenicity: Not known Neurotoxicity: Not known Reproductive hazards: Not known  

Ecological Information

Aquatic toxicity – fish: Unlikely to be hazardous to aquatic life. Aquatic toxicity – daphnia: Unlikely to be hazardous. Aquatic toxicity – algae: Unlikely to be hazardous. Biodegradability: PVC shows no evidence for biodegradability in water or soil. Bio-accumulation: The product has no potential for bioaccumulation. Mobility: The product has no mobility in soil and can be substantially removed from effluent water in biological treatment processes.  

Disposal Considerations

Disposal methods: Disposal should be in accordance with local, regional or national legislation. Disposal of packaging: N/A  

Transport Information

PVC compounds are not listed as hazardous chemical substances and hence is not classified as dangerous for transport.  

Regulatory Information

Risk phrases: R37 – Irritating to respiratory system Safety phrases: S20/21 – When using, do not eat, drink or smoke S22 – Do not breathe dust S45 – In case of an accident or if you do not feel well, seek medical advice immediately S51 – Use only in well-ventilated areas

Product and Company Identification

Trade name: Flame Retarded PVC Compound 135800/135811/135801 Chemical abstract no.: 9002-86-2 Chemical family: Polyvinyl Chloride with additives NIOSH no.: KU9625000 Chemical name: Polyvinyl chloride Synonyms: PVC Compound UN no.: Not classified as hazardous for transport  

Composition

Hazardous components: Polyvinyl Chloride, Antimony Trioxide R Phrases: R37 S Phrases: S20/21; S22; S45; S51  

Hazards Identification

Flame Retarded PVC Compound 135800 / 135811/135801 is a pelletised granule and is either natural or black in colour. The compound has been designed for use as a FR PVC compound on Power Cables and conforms to SABS 1411 Part 2. The compound is very stable in its natural form and the normal precautionary measures should be taken when any contact is made with the material or in case of a fire. Eye effects: Fumes generated during processing may cause irritation. Health effects – skin: None, but avoid prolonged contact. Health effects – ingestion: Harmful as compounds contain lead stabilisers and antimony trioxide. Health effects – inhalation: Fumes generated during processing of PVC compound may cause irritation. Carcinogenicity: Not known Mutagenicity: Not known Neurotoxicity: Not known  

First Aid Measures

Product in eye: Flush eyes with clean water. Medical attention may be necessary if irritation persists. Product on skin: Wash with soap and water. For hot product, flush the affected area with cold water to dissipate heat. Do not remove material from the skin. Get prompt medical attention. Product ingested: Wash out mouth and give plenty of water to drink. Seek medical advice. Product inhaled: Remove from exposure to fresh air. Seek medical advice.  

Fire Fighting Measures

Extinguishing media: CO2, Dry Chemical, Fog or Regular Foam may be used. Special hazards: The product is nonflammable and nonexplosive under normal conditions of use. When forced to burn, the major gaseous products are carbon monoxide, carbon dioxide, hydrogen chloride and water. Flame retardant additives ensure that the minimum quantity of hydrogen chloride is released. Protective clothing: An approved positive pressure self-contained apparatus must be worn.  

Accidental Release Measures

Personal precautions: Pellets may cause slippage on hard surfaces. Environmental precautions: No data is available on the adverse effects of this product on the environment. Small spills: Sweep up and discard in waste containers (recycle if possible). Large spills: May be disposed of by landfill as per local regulations.  

Handling and Storage

Suitable material: Keep stainless steel container tightly closed in a well ventilated place. Handling/storage precautions: Avoid contact with skin and eyes. Keep away from heat and sources of ignition.  

Exposure Controls/Personal Protection

Engineering control measures: Ventilation requirements – local exhaust. Personal protection – respiratory: Use approved dust respirators. Personal protection – hand: Minimise contact with product. Wear gloves. Personal protection – eye: Wear safety glasses with side shields, goggles or face shield for protection against dust. Personal protection – skin: Minimise contact with product. Wear gloves and/or suitable long sleeved clothing.  

Physical and Chemical Properties

Appearance: Pellets or Granules Odour: Faint soap like pH: Not applicable Boiling point: Not applicable Melting point: > 150ºC Flash point: > 450ºC Flammability: N/A Vapour pressure: N/A Density: 1.4 – 1.6 Solubility – water: Insoluble Solubility – solvent: Miscible in Cyclohexanone, Tetrahydofuran  

Stability and Reactivity

Conditions to avoid: Polyvinyl chloride is stable under normal conditions. Incompatible materials: Polyvinyl chloride is incompatible with strong oxidising agents like sulphuric acid (>90%) and nitric acid (>50%). Strong inorganic acids will attack the polymer at temperatures > 60ºC. Halogens like bromine and fluorine attack Polyvinyl chloride at room temperature and can result in violent reactions. Hazardous decomposition products: Thermal decomposition can result in the release of toxic vapours of hydrogen chloride, carbon monoxide and carbon dioxide.  

Toxicological Information

Acute toxicity: High concentrations of dust may irritate the upper respiratory tract. Vapour released during hot processing may cause respiratory irritation. Skin and eye contact: Repeated skin contact can cause irritation and abrasion. Direct eye contact can range from irritation to abrasion. Chronic toxicity: Chronic inhalation of dusts can cause pulmonary damage, blood effects and abnormal liver function. Carcinogenicity: Polyvinyl chloride is a questionable carcinogen with experimental tumorigenic data. Mutagenicity: Not known Neurotoxicity: Not known Reproductive hazards: Not known  

Ecological Information

Aquatic toxicity – fish: Unlikely to be hazardous to aquatic life. Aquatic toxicity – daphnia: Unlikely to be hazardous. Aquatic toxicity – algae: Unlikely to be hazardous. Biodegradability: PVC shows no evidence for biodegradability in water or soil. Bio-accumulation: The product has no potential for bioaccumulation. Mobility: The product has no mobility in soil and can be substantially removed from effluent water in biological treatment processes.  

Disposal Considerations

Disposal methods: Disposal should be in accordance with local, regional or national legislation. Disposal of packaging: N/A  

Transport Information

PVC compounds are not listed as hazardous chemical substances and hence are not classified as dangerous for transport.  

Regulatory Information

Risk phrases: R37 – Irritating to respiratory system Safety phrases: S20/21 – When using, do not eat, drink or smoke S22 – Do not breathe dust S45 – In case of an accident or if you do not feel well, seek medical advice immediately S51 – Use only in well-ventilated areas

Product and Company Identification

LOW HALOGEN FIRE RETARDANT PVC COMPOUND (Page 1 may be used as an emergency safety sheet) Trade name: Low Halogen PVC Compound 135900 / 135901 Chemical abstract no.: 9002-86-2 Chemical family: Polyvinyl Chloride with additives NIOSH no.: KU9625000 Chemical name: Polyvinyl chloride Synonyms: PVC Compound UN no.: Not classified as hazardous for transport  

Composition

Hazardous components: Polyvinyl Chloride, Antimony Trioxide R Phrases: R37 S Phrases: S20/21; S22; S45; S51  

Hazards Identification

Low Halogen PVC Compound 135900 / 135901 is a pelletised granule and is either natural or black in colour. The compound has been designed for use as a low halogen PVC compound on Power Cables and conforms to SABS 1411 Part 2. The compound is very stable in its natural form and the normal precautionary measures should be taken when any contact is made with the material or in case of a fire. Eye effects: Fumes generated during processing may cause irritation. Health effects – skin: None, but avoid prolonged contact. Health effects – ingestion: Harmful as compounds contain lead stabilisers and antimony trioxide. Health effects – inhalation: Fumes generated during processing of PVC compound may cause irritation. Carcinogenicity: Not known Mutagenicity: Not known Neurotoxicity: Not known  

First Aid Measures

Product in eye: Flush eyes with clean water. Medical attention may be necessary if irritation persists. Product on skin: Wash with soap and water. For hot product, flush the affected area with cold water to dissipate heat. Do not remove material from the skin. Get prompt medical attention. Product ingested: Wash out mouth and give plenty of water to drink. Seek medical advice. Product inhaled: Remove from exposure to fresh air. Seek medical advice.  

Fire Fighting Measures

Extinguishing media: CO2, Dry Chemical, Fog or Regular Foam may be used. Special hazards: The product is nonflammable and nonexplosive under normal conditions of use. When forced to burn, the major gaseous products are carbon monoxide, carbon dioxide, hydrogen chloride and water. Flame retardant additives ensure that the minimum quantity of hydrogen chloride is released. Protective clothing: An approved positive pressure self-contained apparatus must be worn.  

Accidental Release Measures

Personal precautions: Pellets may cause slippage on hard surfaces. Environmental precautions: No data is available on the adverse effects of this product on the environment. Small spills: Sweep up and discard in waste containers (recycle if possible). Large spills: May be disposed of by landfill as per local regulations.  

Handling and Storage

Suitable material: Keep stainless steel container tightly closed in a well ventilated place. Handling/storage precautions: Avoid contact with skin and eyes. Keep away from heat and sources of ignition.  

Exposure Controls/Personal Protection

Engineering control measures: Ventilation requirements – local exhaust. Personal protection – respiratory: Use approved dust respirators. Personal protection – hand: Minimise contact with product. Wear gloves. Personal protection – eye: Wear safety glasses with side shields, goggles or face shield for protection against dust. Personal protection – skin: Minimise contact with product. Wear gloves and/or suitable long sleeved clothing.  

Physical and Chemical Properties

Appearance: Pellets or Granules Odour: Faint soap like pH: Not applicable Boiling point: Not applicable Melting point: > 150ºC Flash point: > 450ºC Flammability: N/A Vapour pressure: N/A Density: 1.4 – 1.6 Solubility – water: Insoluble Solubility – solvent: Miscible in Cyclohexanone, Tetrahydrofuran  

Stability and Reactivity

Conditions to avoid: Polyvinyl chloride is stable under normal conditions. Incompatible materials: Polyvinyl chloride is incompatible with strong oxidising agents like sulphuric acid (>90%) and nitric acid (>50%). Strong inorganic acids will attack the polymer at temperatures > 60ºC. Halogens like bromine and fluorine attack Polyvinyl chloride at room temperature and can result in violent reactions. Hazardous decomposition products: Thermal decomposition can result in the release of toxic vapours of hydrogen chloride, carbon monoxide and carbon dioxide.  

Toxicological Information

Acute toxicity: High concentrations of dust may irritate the upper respiratory tract. Vapour released during hot processing may cause respiratory irritation. Skin and eye contact: Repeated skin contact can cause irritation and abrasion. Direct eye contact can range from irritation to abrasion. Chronic toxicity: Chronic inhalation of dusts can cause pulmonary damage, blood effects and abnormal liver function. Carcinogenicity: Polyvinyl chloride is a questionable carcinogen with experimental tumorigenic data. Mutagenicity: Not known Neurotoxicity: Not known Reproductive hazards: Not known  

Ecological Information

Aquatic toxicity – fish: Unlikely to be hazardous to aquatic life. Aquatic toxicity – daphnia: Unlikely to be hazardous. Aquatic toxicity – algae: Unlikely to be hazardous. Biodegradability: PVC shows no evidence for biodegradability in water or soil. Bio-accumulation: The product has no potential for bioaccumulation. Mobility: The product has no mobility in soil and can be substantially removed from effluent water in biological treatment processes.  

Disposal Considerations

Disposal methods: Disposal should be in accordance with local, regional or national legislation. Disposal of packaging: N/A  

Transport Information

PVC compounds are not listed as hazardous chemical substances and hence are not classified as dangerous for transport.  

Regulatory Information

Risk phrases: R37 – Irritating to respiratory system Safety phrases: S20/21 – When using, do not eat, drink or smoke S22 – Do not breathe dust S45 – In case of an accident or if you do not feel well, seek medical advice immediately S51 – Use only in well-ventilated areas

Product and Company Identification

(Page 1 may be used as an emergency safety sheet) Trade name: Aluminium Strand Chemical abstract no.: None Chemical family: Aluminium, Aluminium Alloy NIOSH no.: None Chemical name: Hazchem code: None Synonyms: Aluminium UN no.: None  

Composition

Hazardous components: – EEC classification: –  

Hazards Identification

Eyes effects: None Health effects – skin: None Health effects – ingestion: None Health effects – inhalation: None Carcinogenicity: – Mutagenicity: –  

First Aid Measures

Product in eye: Not expected to require first aid measures Product on skin: Not expected to require first aid measures Product ingested: Not expected to require first aid measures Product inhaled: Not expected to require first aid measures  

Fire Fighting Measures

Extinguishing media: Carbon dioxide, dry chemical powder or foam Special hazards: Irritant fumes. Protective clothing: None.  

Accidental Release Measures

Personal precautions: Spilt product presents a significant slip hazard. Environmental precautions: Prevent materials entering drain sewers. Decontamination procedures: Soak up with inert absorbent or contain and remove by best available means.  

Handling and Storage

Suitable material: Do not eat, drink or smoke whilst using this product. To avoid the possibility of skin disorders, repeated or prolonged contact with the product should be avoided. It is essential to maintain a high standard of personal hygiene. Handling/storage precautions: Store out of direct sunlight.  

Exposure Controls/Personal Protection

Engineering control measures: Ventilation requirements – local exhaust Personal protection – respiratory: Use approved dust respirators Personal protection – hand: Minimise contact with product. Wear gloves. Personal protection – eye: Wear safety glasses. Personal protection – skin: Minimise contact with product. Wear gloves and/or suitable long sleeved clothing.  

Physical and Chemical Properties

Appearance: Bright, silver coloured metal Odour: Mild pH: N/A Boiling point: 2327 °C Melting point: 660°C typical Flash point: 200°C typical Flammability: None Autoflammability: None Explosive properties: None Oxidizing properties: Not applicable Vapour pressure: None Density: 2.70 g/cm3 Solubility – water: Insoluble  

Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage Conditions to avoid: Reaction with incompatibles Materials to avoid: Mercury, Halocarbons, Halogens, Strong oxidising agents, Some acids, Bases and other materials Hazardous decomposition products: Toxic fumes may form when heated to decomposition  

Toxicological Information

Acute toxicity: Not known Skin and eye contact: Not known Chronic toxicity: Not known Carcinogenicity: Not known Mutagenicity: Not known Neurotoxicity: Not known Reproductive hazards: Not known  

Ecological Information

Aquatic toxicity – fish: Unlikely to be hazardous to aquatic life Aquatic toxicity – daphnia: Unlikely to be hazardous Aquatic toxicity – algae: Unlikely to be hazardous Biodegradability: Not known Bio-accumulation: The product has no potential for bioaccumulation. Mobility: The product has no mobility in soil and can be substantially removed from effluent water in biological treatment processes  

Disposal Considerations

Disposal methods: Disposal should be in accordance with local, regional or national legislation. Disposal of packaging: N/A  

Transport Information

PVC compounds are not listed as hazardous chemical substances and hence are not classified as dangerous for transport.

Product and Company Identification

(Page 1 may be used as an emergency safety sheet) Trade name: Copper Rod Chemical abstract no.: None Chemical family: NIOSH no.: None Chemical name: Copper Hazchem code: None Synonyms: Copper Rod and Cathode UN no.: None  

Composition

Hazardous components: Copper 99.99% EEC classification: –  

Hazards Identification

Main hazard: Irritant Health effects – inhalation: Ulceration and perforation of the nasal septum from copper fumes  

First Aid Measures

Product ingested: Spontaneous vomiting will occur. Product inhaled: Remove to fresh air. Call doctor immediately.  

Fire Fighting Measures

Not applicable.  

Accidental Release Measures

Personal precautions: None Environmental precautions: None Decontamination procedures: None  

Handling and Storage

Handling/storage precautions: Store in appropriate location.  

Exposure Controls/Personal Protection

Engineering control measures: Ventilation requirements – local exhaust Personal protection – respiratory: Use approved dust respirators Personal protection – hand: Minimise contact with product. Wear gloves. Personal protection – eye: Wear safety glasses. Personal protection – skin: Minimise contact with product. Wear gloves and/or suitable long sleeved clothing.  

Physical and Chemical Properties

Appearance: Golden Brown Metal Odour: None pH: N/A Melting point: 1083°C typical Flammability: None Density: 8.89 g/cm3 Solubility – water: Insoluble  

Stability and Reactivity

Stability: Stable Conditions to avoid: Presence of Nitric Acid Materials to avoid: Magnesium metal and acetylene gas Hazardous decomposition products: None  

Toxicological Information

Acute toxicity: None Skin and eye contact: None Chronic toxicity: None Carcinogenicity: Not known Mutagenicity: Not known Neurotoxicity: Not known Reproductive hazards: Not known  

Ecological Information

Aquatic toxicity – fish: Unlikely to be hazardous to aquatic life Aquatic toxicity – daphnia: Unlikely to be hazardous Aquatic toxicity – algae: Unlikely to be hazardous Biodegradability: None Bio-accumulation: None Mobility: Copper is a micronutrient  

Disposal Considerations

Disposal methods: Copper metal is readily recycled. Disposal of packaging: N/A  

Transport Information

Not hazardous.

Product and Company Identification

(Page 1 may be used as an emergency safety sheet) Trade name: Insulating Paper Chemical abstract no.: None Chemical family: NIOSH no.: None Chemical name: Paper Hazchem code: None Synonyms: Paper UN no.: None  

Composition

Hazardous components: – EEC classification: –  

Hazards Identification

Main hazard: None Flammability: Not flammable Chemical hazard: None Biological hazard: None Reproductive hazard: None Eye effects: None Health effects – skin: None Health effects – ingestion: None Health effects – inhalation: None Carcinogenicity: – Mutagenicity: –  

First Aid Measures

Product in eye: Not required Product on skin: Not required Product ingested: Not required Product inhaled: Not required  

Fire Fighting Measures

Extinguishing media: Water, Carbon dioxide, dry chemical powder or foam Special hazards: None Protective clothing: None  

Accidental Release Measures

Personal precautions: No special measures required Environmental precautions: Not required Decontamination procedures: No special measures required  

Handling and Storage

Handling: Caution when handling heavy rolls, no further requirements Storage: Store in dry conditions  

Exposure Controls/Personal Protection

Technical measures for exposure controls: No requirements  

Physical and Chemical Properties

Appearance: Natural or black Odour: Mild pH: 6–8 in aqueous solution Boiling point: N/A Melting point: N/A Flash point: No development of volatile and inflammable vapours till combustion Flammability: None Autoflammability: None Explosive properties: None Oxidizing properties: Not applicable Vapour pressure: None Density: 0.8–1.1 g/cm³ Solubility – water: Insoluble  

Stability and Reactivity

Conditions to avoid: None Materials to avoid: None Hazardous decomposition products: None  

Toxicological Information

Acute toxicity: Non-toxic Skin and eye contact: – Chronic toxicity: – Carcinogenicity: – Mutagenicity: – Neurotoxicity: – Reproductive hazards: –  

Ecological Information

Aquatic toxicity – fish: Unlikely to be hazardous to aquatic life Aquatic toxicity – daphnia: Unlikely to be hazardous Aquatic toxicity – algae: Unlikely to be hazardous Biodegradability: Decomposes in nature Bio-accumulation: – Mobility: –  

Disposal Considerations

Disposal methods: Disposal should be in accordance with local, regional or national legislation.  

Transport Information

Paper is not classified as dangerous for transport.  

Regulatory Information

Risk phrases: None Safety phrases: None

Product and Company Identification

(Page 1 may be used as an emergency safety sheet) Trade name: Cable Lead Chemical abstract no.: None Chemical family: Group IV NIOSH no.: None Chemical name: Lead Hazchem code: None Synonyms: Lead alloys UN no.: None  

Composition

Hazardous components: Lead (0.15 mg/m³); Tin (2 mg/m³); Antimony (0.5 mg/m³); Copper (0.1 mg/m³); Selenium (0.1 mg/m³) EEC classification: – R Phrases: R33  

Hazards Identification

Main hazard: Lead dust; OEL 0.15 mg/m³ Flammability: None Chemical hazard: Lead salts poisonous Biological hazard: None Reproductive hazard: None Eyes effects: Irritation due to dust Health effects – skin: Can leave deposit on skin if handled without gloves Health effects – ingestion: None Health effects – inhalation: Dust. OEL 0.15 mg/m³ Carcinogenicity: – Mutagenicity: –  

First Aid Measures

Product in eye: Wash with water Product on skin: Remove with detergent Product ingested: Do not induce vomiting. Obtain medical help. Product inhaled: Not applicable, except for lead dust. Obtain medical help.  

Fire Fighting Measures

Extinguishing media: Non-combustible Special hazards: Can give rise to hazardous fumes in a fire. Protective clothing: Normal work wear.  

Accidental Release Measures

Personal precautions: Wear appropriate protective clothing. Environmental precautions: Prevent materials entering drain sewers. Small spills: Allow to solidify if molten, remove to suitable containers. Large spills: Allow to solidify if molten, remove to suitable containers.  

Handling and Storage

Suitable material: Steel drums. Steel straps. Handling/storage precautions: Bundles  

Exposure Controls/Personal Protection

Engineering control measures: Ventilation requirements – local exhaust Personal protection – respiratory: Use approved dust respirators Personal protection – hand: Minimise contact with product. Wear gloves. Personal protection – eye: Wear safety glasses with side shields, goggles, or face shield Personal protection – skin: Minimise contact with product. Wear gloves and/or long-sleeved clothing  

Physical and Chemical Properties

Appearance: Silver ingots Odour: None pH: N/A Boiling point: 1740 °C Melting point: 327 °C Flash point: None Flammability: None Autoflammibility: None Explosive properties: None Oxidizing properties: Forms oxide layer on exposure to air Vapour pressure: None Density: 11.37 tonnes/m³ Solubility – water: Insoluble Solubility – solvent: Nitric Acid  

Stability and Reactivity

Conditions to avoid: None. Incompatible materials: None Hazardous decomposition products: Lead oxide formed under oxidising conditions.  

Toxicological Information

Acute toxicity: Vomiting, malaise Skin and eye contact: Irritation, causing discomfort. Chronic toxicity: Weight loss, anemia. Carcinogenicity: Not known Mutagenicity: Not known Neurotoxicity: Not known Reproductive hazards: Not known  

Ecological Information

Aquatic toxicity – fish: Unlikely to be hazardous to aquatic life Aquatic toxicity – daphnia: Unlikely to be hazardous Aquatic toxicity – algae: Unlikely to be hazardous Biodegradability: Lead shows no evidence for biodegradability in water or soil Bio-accumulation: No potential for bioaccumulation. Mobility: No mobility in soil; can be removed from effluent water in biological treatment processes  

Disposal Considerations

Disposal methods: Disposal should be in accordance with local, regional or national legislation. Disposal of packaging: N/A  

Transport Information

Alloy E lead is not listed as a hazardous chemical substance and is not classified as dangerous for transport.  

Regulatory Information

Risk phrases: R33 Safety phrases: S20/21 – When using, do not eat, drink or smoke S22 – Do not breathe dust

Product and Company Identification

(Page 1 may be used as an emergency safety sheet) Trade name: Non Draining Power Cable Insulation Media Chemical abstract no.: None Chemical family: Blend of mineral oils, axes, rosin colophony and additives NIOSH no.: None Chemical name: Hazchem code: None Synonyms: MIND UN no.: None  

Composition

Hazardous components: Rosin, Colophony EEC classification: –  

Hazards Identification

Main hazard: Irritant Flammability: It is flammable above 200°C Chemical hazard: Irritant Biological hazard: None Reproductive hazard: None Eyes effects: Irritation Health effects – skin: Can leave deposit on skin if handled without gloves Health effects – ingestion: None Health effects – inhalation: None Carcinogenicity: – Mutagenicity: –  

First Aid Measures

Product in eye: Wash with water Product on skin: Remove with detergent Product ingested: Do not induce vomiting. Obtain medical help. Product inhaled: Remove from exposure  

Fire Fighting Measures

Extinguishing media: Carbon dioxide, dry chemical powder or foam Special hazards: Irritant fumes. Protective clothing: None.  

Accidental Release Measures

Personal Precautions: Spilt product presents a significant slip hazard. Environmental precautions: Prevent materials entering drain sewers. Decontamination Procedures: Soak up with inert absorbent or contain and remove by best available means.  

Handling and Storage

Suitable material: Do not eat, drink or smoke whilst using this product. Handling/storage precautions: Store out of direct sunlight. To avoid the possibility of skin disorders, repeated or prolonged contact with the product should be avoided. Maintain a high standard of personal hygiene.  

Exposure Controls/Personal Protection

Engineering control measures: Ventilation requirements – local exhaust Personal protection – respiratory: Use approved dust respirators Personal protection – hand: Minimise contact with product. Wear gloves. Personal protection – eye: Wear safety glasses. Personal protection – skin: Minimise contact with product. Wear gloves and/or suitable long sleeved clothing  

Physical and Chemical Properties

Appearance: Brown waxy solid Odour: Mild pH: N/A Boiling point: >300°C Melting point: 98°C typical Flash point: 200°C typical Flammability: None Autoflammibility: None Explosive properties: None Oxidizing properties: Not applicable Vapour pressure: None Density: 0.87 g/cm3 Solubility – water: Insoluble  

Stability and Reactivity

Stability: Stable up to boiling point Conditions to avoid: Any source of ignition Materials to avoid: Strong oxidising agents Hazardous decomposition products: Oxides of carbon. Irritant fumes.  

Toxicological Information

Acute toxicity: Vomiting, malaise Skin and eye contact: Irritation, causing discomfort. Chronic toxicity: Weight loss, anemia. Carcinogenicity: Not known Mutagenicity: Not known Neurotoxicity: Not known Reproductive hazards: Not known  

Ecological Information

Aquatic toxicity – fish: Unlikely to be hazardous to aquatic life Aquatic toxicity – daphnia: Unlikely to be hazardous Aquatic toxicity – algae: Unlikely to be hazardous Biodegradability: Not readily biodegradable, but is inherently biodegradable Mobility: The product has no mobility in soil and can be substantially removed from effluent water in biological treatment processes  

Disposal Considerations

Disposal methods: Disposal should be in accordance with local, regional or national legislation. Disposal of packaging: N/A  

Transport Information

Not classified as dangerous for transport.

Product and Company Identification

(Page 1 may be used as an emergency safety sheet) Trade name: XLPE Chemical abstract no.: 009002-88-4 Chemical family: Crosslinked polyethylene, LLDPE, MDPE, HDPE, PP fillers NIOSH no.: None Chemical name: Polyethylene Homopolymer Hazchem code: None Synonyms: Polyethylene UN no.: None  

Composition

Hazardous components: None EEC classification: –  

Hazards Identification

Flammability: The product burns, but is not classified as flammable. Environmental hazard: Not considered dangerous to the environment. Health effects: The product is not classified as hazardous.  

First Aid Measures

Product in eye: Wash with water. Product on skin: Wash with water. Product ingested: Do not induce vomiting. Obtain medical help. Product inhaled: Remove from exposure.  

Fire Fighting Measures

Extinguishing media: Carbon dioxide, dry chemical powder or foam. Special hazards: Dense smoke; principal toxicant is carbon monoxide. Protective clothing: None.  

Accidental Release Measures

Personal precautions: Spilt product presents a significant slip hazard. Environmental precautions: Prevent materials entering drain sewers.  

Handling and Storage

Suitable material: Do not eat, drink or smoke while using this product. To avoid skin disorders, avoid repeated or prolonged contact. Maintain good personal hygiene. Handling/storage precautions: Store out of direct sunlight.  

Exposure Controls/Personal Protection

Engineering control measures: Ventilation requirements – local exhaust. Personal protection – respiratory: Use approved dust respirators. Personal protection – hand: Minimise contact with product. Wear gloves. Personal protection – eye: Wear safety glasses. Personal protection – skin: Minimise contact with product. Wear gloves and/or suitable long-sleeved clothing.  

Physical and Chemical Properties

Appearance: Shiny plastic. Colour: Any colour ranging from black to white. pH: N/A Boiling point: – Melting point: 110 – 140°C typical Flash point: >300°C typical Flammability: None Autoflammability: None Explosive properties: None Oxidizing properties: Not applicable Vapour pressure: None Density: 0.9 – 1.0 g/cm³ Solubility – water: Insoluble  

Stability and Reactivity

Stability: Stable thermoplastic. Conditions to avoid: Excessive heat. Hazardous decomposition products: Hydrocarbons.  

Toxicological Information

Acute toxicity: None. Skin and eye contact: Irritation causing discomfort. Chronic toxicity: Not known. Carcinogenicity: Not known. Mutagenicity: Not known. Neurotoxicity: Not known. Reproductive hazards: Not known.  

Ecological Information

Aquatic toxicity – fish: Unlikely to be hazardous to aquatic life. Aquatic toxicity – daphnia: Unlikely to be hazardous. Aquatic toxicity – algae: Unlikely to be hazardous. Bio-accumulation: The product has no potential for bioaccumulation. Mobility: No mobility in soil; can be substantially removed in biological water treatment.  

Disposal Considerations

Disposal methods: Disposal must follow local, regional or national legislation. Disposal of packaging: N/A  

Transport Information

XLPE compounds are not classified as hazardous and are not dangerous for transport.

Product and Company Identification

(Page 1 may be used as an emergency safety sheet) Trade name: XLPE Chemical abstract no.: 009002-88-4 Chemical family: Crosslinked polyethylene, LLDPE, MDPE, HDPE, PP fillers NIOSH no.: None Chemical name: Polyethylene Homopolymer Hazchem code: None Synonyms: Polyethylene UN no.: None  

Composition

Hazardous components: None EEC classification: –  

Hazards Identification

Flammability: The product burns, but is not classified as flammable. Environmental hazard: Not considered dangerous to the environment. Health effects: The product is not classified as hazardous.  

First Aid Measures

Product in eye: Wash with water. Product on skin: Wash with water. Product ingested: Do not induce vomiting. Obtain medical help. Product inhaled: Remove from exposure.  

Fire Fighting Measures

Extinguishing media: Carbon dioxide, dry chemical powder or foam. Special hazards: Dense smoke; principal toxicant is carbon monoxide. Protective clothing: None.  

Accidental Release Measures

Personal precautions: Spilt product presents a significant slip hazard. Environmental precautions: Prevent materials entering drain sewers.  

Handling and Storage

Suitable material: Do not eat, drink or smoke whilst using this product. To avoid skin disorders, avoid repeated or prolonged contact. Maintain a high standard of personal hygiene. Handling/storage precautions: Store out of direct sunlight.  

Exposure Controls/Personal Protection

Engineering control measures: Ventilation requirements – local exhaust. Personal protection – respiratory: Use approved dust respirators. Personal protection – hand: Minimise contact with product. Wear gloves. Personal protection – eye: Wear safety glasses. Personal protection – skin: Minimise contact with product. Wear gloves and/or suitable long sleeved clothing.  

Physical and Chemical Properties

Appearance: Shiny plastic. Colour: Any colour ranging from black to white. pH: N/A Boiling point: – Melting point: 110–140°C typical Flash point: >300°C typical Flammability: None Autoflammibility: None Explosive properties: None Oxidizing properties: Not applicable Vapour pressure: None Density: 0.9–1.0 g/cm³ Solubility – water: Insoluble  

Stability and Reactivity

Stability: Stable thermoplastic. Conditions to avoid: Excessive heat. Hazardous decomposition products: Hydrocarbons.  

Toxicological Information

Acute toxicity: None. Skin and eye contact: Irritation causing discomfort. Chronic toxicity: Not known. Carcinogenicity: Not known. Mutagenicity: Not known. Neurotoxicity: Not known. Reproductive hazards: Not known.  

Ecological Information

Aquatic toxicity – fish: Unlikely to be hazardous to aquatic life. Aquatic toxicity – daphnia: Unlikely to be hazardous. Aquatic toxicity – algae: Unlikely to be hazardous. Bio-accumulation: No potential for bioaccumulation. Mobility: No mobility in soil; removable via biological treatment.  

Disposal Considerations

Disposal methods: Dispose according to local, regional or national legislation. Disposal of packaging: N/A  

Transport Information

XLPE compounds are not listed as hazardous chemical substances and are not classified as dangerous for transport.

Product and Company Identification

(Page 1 may be used as an emergency safety sheet) Trade name: Cable Lead Chemical abstract no.: None Chemical family: Group IV NIOSH no.: None Chemical name: Lead Hazchem code: None Synonyms: Lead alloys UN no: None  

Composition

Hazardous components: Lead (0.15 mg/m3); Tin (2 mg/m3); Antimony (0.5 mg/m3); Copper (0.1 mg/m3); Selenium (0.1 mg/m3); Lead EEC classification: – R Phrases: R33  

Hazards Identification

Main hazard: Lead dust; OEL 0.15 mg/m3 Flammability: None Chemical hazard: Lead salts poisonous Biological hazard: None Reproductive hazard: None Eye effects: Irritation due to dust Health effects – skin: Can leave deposit on skin if handled without gloves Health effects – ingestion: None Health effects – inhalation: Dust. OEL 0.15 mg/m3 Carcinogenicity: – Mutagenicity: –  

First Aid Measures

Product in eye: Wash with water. Product on skin: Remove with detergent. Product ingested: Do not induce vomiting. Obtain medical help. Product inhaled: Not applicable, except for lead dust. Obtain medical help.  

Fire Fighting Measures

Extinguishing media: Non combustible. Special hazards: Can give rise to hazardous fumes in a fire. Protective clothing: Normal work wear.  

Accidental Release Measures

Personal precautions: Wear appropriate protective clothing. Environmental precautions: Prevent materials entering drain sewers. Small spills: Allow to solidify if molten, remove to suitable containers. Large spills: Allow to solidify if molten, remove to suitable containers.  

Handling and Storage

Suitable material: Steel drums. Steel straps. Handling/storage precautions: Bundles.  

Exposure Controls / Personal Protection

Engineering control measures: Ventilation requirements – local exhaust. Personal protection – respiratory: Use approved dust respirators. Personal protection – hand: Minimise contact with product. Wear gloves. Personal protection – eye: Wear safety glasses with side shields, goggles or face shield for protection against dust. Personal protection – skin: Minimise contact with product. Wear gloves and/or suitable long sleeved clothing.  

Physical and Chemical Properties

Appearance: Silver ingots Odour: None pH: N/A Boiling point: 1740°C Melting point: 327°C Flash point: None Flammability: None Autoflammibility: None Explosive properties: None Oxidizing properties: Forms oxide layer on exposure to air Vapour pressure: None Density: 11.37 tonnes/m3 Solubility – water: Insoluble Solubility – solvent: Nitric Acid  

Stability and Reactivity

Conditions to avoid: None. Incompatible materials: None. Hazardous decomposition products: Lead oxide formed under oxidising conditions.  

Toxicological Information

Acute toxicity: Vomiting, malaise. Skin and eye contact: Irritation, causing discomfort. Chronic toxicity: Weight loss, anemia. Carcinogenicity: Not known. Mutagenicity: Not known. Neurotoxicity: Not known. Reproductive hazards: Not known.  

Ecological Information

Aquatic toxicity – fish: Unlikely hazardous to aquatic life. Aquatic toxicity – daphnia: Unlikely to be hazardous. Aquatic toxicity – algae: Unlikely to be hazardous. Biodegradability: Lead shows no evidence for biodegradability in water or soil. Bioaccumulation: The product has no potential for bioaccumulation. Mobility: The product has no mobility in soil and can be removed from effluent water in biological treatment processes.  

Disposal Considerations

Disposal methods: Disposal should be in accordance with local, regional or national legislation. Disposal of packaging: N/A  

Transport Information

Alloy E lead is not listed as a hazardous chemical substance and hence is not classified as dangerous for transport.  

Regulatory Information

Risk phrases: R33 Safety phrases: S20/21 – When using, do not eat, drink or smoke S22 – Do not breathe dust

Product and Company Identification

(Page 1 may be used as an emergency safety sheet) Trade name: Low Halogen PVC Compound 135300 Chemical abstract no.: 9002-86-2 Chemical family: Polyvinyl Chloride with additives NIOSH no.: KU9625000 Chemical name: Polyvinyl chloride Synonyms: PVC Compound  

Composition

UN no.: Not clas Hazardous components: Polyvinyl Chloride, Antimony Trioxide R Phrases: R37  

Hazards Identification

Hard Grade PVC Compound 135300 is a pelletised granule and is either natural or black in colour. The compound has been designed for use as a low halogen PVC compound on Power Cables and conforms to SABS 1411 Part 2. The compound is very stable in its natural form and the normal precautionary measures should be taken when any contact is made with the material or in case of a fire. Eye effects: eyes: Fumes generated during processing may cause irritation Health effects – skin: None, but avoid prolonged contact. Health effects – ingestion: Harmful as compounds contain lead stabilisers and antimony trioxide. Health effects – inhalation: Fumes generated during processing of PVC compound may cause irritation. Carcinogenicity: Not known Mutagenicity: Not known Neurotoxicity: Not known  

First Aid Measures

Product in eye: Flush eyes with clean water. Medical attention may be necessary if irritation persists. Product on skin: Wash with soap and water. For hot product, flush the affected area with cold water to dissipate heat. Do not remove material from the skin. Get prompt medical attention. Product ingested: Wash out mouth and give plenty of water to drink. Seek medical advice. Product inhaled: Remove from exposure to fresh air. Seek medical advice.  

Fire Fighting Measures

Extinguishing media: CO2, Dry Chemical, Fog or Regular Foam may be used. Special hazards: The product is nonflammable and nonexplosive under normal conditions of use. When forced to burn, the major gaseous products are carbon monoxide, carbon dioxide, hydrogen chloride and water. Flame retardant additives ensure that the minimum quantity of hydrogen chloride is released. Protective clothing: An approved positive pressure self-contained apparatus must be worn.  

Accidental Release Measures

Personal precautions: Pellets may cause slippage on hard surfaces Environmental precautions: No data is available on the adverse effects of this product on the enviroment. Small spills: Sweep up and discard in waste containers (recycle if possible). Large spills: May be disposed of by landfill as per local regulations  

Handling and Storage

Suitable material: Keep stainless steel container tightly closed in a well ventilated place. Handling/storage precautions: Avoid contact with skin and eyes. Keep away from heat and sources of ignition.  

Exposure Controls/Personal Protection

Engineering control measures: Ventilation requirements – local exhaust Personal protection – respiratory: Use approved dust respirators Personal protection – hand: Minimise contact with product. Wear gloves. Personal protection – eye: Wear safety glasses with side shields, goggles or face shield for protection against dust Personal protection – skin: Minimise contact with product. Wear gloves and / or suitable long sleeved clothing  

Physical and Chemical Properties

Appearance: Pellets or Granules Odour: Faint soap like pH: Not applicable Boiling point: Not applicable Melting point: > 150ºC Flash point: > 450ºC Flammability: N/A Vapour pressure: N/A Density: 1.4 – 1.6 Solubility – water: Insoluble Solubility – solvent: Miscible in Cyclohexanone, Tetrahydofuran  

Stability and Reactivity

Conditions to avoid: Polyvinyl chloride is stable under normal conditions. Incompatible materials: Polyvinyl chloride is incompatible with strong oxididsing agents like sulphuric acid (>90%) and nitric acid (>50%). Strong inorganic acids will attack the polymer at temperatures > 60ºC. Halogens like romine and fluorine attack Polyvinyl chloride at room temperature and can result in violent reactions. Hazardous decomposition products: Thermal decomposition can result in the release of toxic vapours of hydrogen chloride, carbon monoxide and carbon dioxide.  

Toxicological Information

Acute toxicity: High concentrations of dust may irritate the upper respiratory tract. Vapour released during hot processing may cause respiratory irritation. Skin and eye contact: Repeated skin contact can cause irritation and abrasion. Direct eye contact can range from irritation to abrasion Chronic toxicity: Chronic inhalation of dusts can cause pulmonary damage, blood effects and abnormal liver function. Carcinogenicity: Polyvinyl chloride is a questionable carcinogen with experimental tumorigenic data. Mutagenicity: Not known Neurotoxicity: Not known Reproductive hazards: Not known  

Ecological Information

Aquatic toxicity – fish: Unlikely to be hazardous to aquatic life Aquatic toxicity – daphnia: Unlikely to be hazardous Aquatic toxicity – algae: Unlikely to be hazardous Biodegradability: PVC shows no evidence for biodegradability in water or soil Bio-accumulation: The product has no potential for bioaccumulation. Mobility: The product has no mobility in soil and can be substantially removed from effluent water in biological treatment processes  

Disposal Considerations

Disposal methods: Disposal should be in accordance with local, regional or national legislation. Disposal of packaging: N/A  

Transport Information

PVC compounds are not listed as hazardous chemical substances and hence is not classified as dangerous for transport.  

Regulatory Information

Risk phrases: R37 – Irritating to respiratory system Safety phrases: S20/21 – When using, do not eat, drink or smoke S22 – Do not breathe dust S45 – In case of an accident or if you do not feel well, seek medical advice immediately S51 – Use only in well-ventilated areas

Composition

Composition: Linear alkylbenzene. All constituents of this product are listed in EINECS (European Inventory of Existing Commercial Chemical Substances) or ELINCS (European List of New Chemical Substances) or are exempt. Refer to Section 8 for Occupational Exposure Limits. None of the ingredients of this product are classified as hazardous.  

Hazards Identification

This product is not classified as hazardous.  

First Aid Measures

Eyes: Irrigate immediately with copious quantities of water for several minutes. Obtain medical attention if irritation persists. Skin: Wash thoroughly with soap and water or suitable skin cleanser as soon as possible. Obtain medical attention if irritation persists. Inhalation: Remove from exposure. Ingestion: Wash out mouth with water. Do not induce vomiting. Obtain medical attention urgently.  

Fire Fighting Measures

Suitable Extinguishing Media: Carbon dioxide, powder, foam or water fog. Do not use water jets. Special Exposure Hazards: Irritant fumes. Carbon monoxide may be generated if the product is burned in an enclosed space. Special Protective Equipment: Self-contained breathing apparatus is recommended.  

Accidental Release Measures

Personal Precautions: Spilt product presents a significant slip hazard. Environmental Precautions: Prevent entry into drains, sewers and watercourses. Decontamination Procedures: Soak up with inert absorbent or contain and remove by best available means.  

Handling and Storage

Handling: Do not eat, drink, or smoke whilst using this product. To avoid skin disorders repeated or prolonged contact must be avoided. Maintain a high standard of personal hygiene. Storage: Store in a cool place away from heat and out of direct sunlight to avoid pressure build-up.  

Exposure Controls/Personal Protection

Occupational Exposure Limits: Engineering Control Measures: Local exhaust ventilation is recommended. Personal Protective Equipment: Avoid skin and eye contact. Wear impervious gloves (e.g., PVC) in case of repeated or prolonged contact. Replace gloves regularly. Change contaminated clothing. Maintain good personal hygiene.  

Physical and Chemical Properties

Physical State: Liquid Colour: Colourless Odour: Mild Boiling Point/Range: 280°C Pour Point: Below -50°C Flash Point (closed): Typically 140°C Vapour Pressure: Below 0.2 mbar at 20°C Density at 20°C: Typically 0.85 g/cm³ Water Solubility: Insoluble  

Stability and Reactivity

Stability: Stable, will not polymerise. Conditions to Avoid: Temperatures above 140°C. Materials to Avoid: Strong oxidising agents. Hazardous Decomposition Products: Carbon monoxide and irritant fumes may be generated if burned in an enclosed space.  

Toxicological Information

Health Effects On Eyes: May cause transient irritation. On Skin: Unlikely to cause injury upon brief contact. Repeated or prolonged contact may cause skin disorders. By Inhalation: Unlikely to present a hazard at ambient temperatures. By Ingestion: May cause nausea, vomiting and diarrhoea. Chronic: Repeated skin contact may lead to skin disorders. Other: None known.  

Ecological Information

Environmental Assessment: No adverse environmental effects are foreseen when used as intended. Mobility: Mobile liquid. Insoluble in water. Degradability: Readily biodegradable. Bioaccumulative Potential: Unlikely due to low water solubility. Ecotoxicity: Not expected to be ecotoxic to fish, daphnia, algae or sewage bacteria.  

Disposal Considerations

Disposal must comply with local and national legislation. Unused Product: Dispose of appropriately. May be incinerated. Used/Contaminated Product: Dispose through authorised waste contractor. May be incinerated. Packaging: Dispose through authorised waste contractor. May be steam cleaned and recycled.  

Transport Information

This product is not classified as dangerous for transport.  

Regulatory Information

Hazard Label Data: Not classified as dangerous. EC Directives: Safety Framework Directive, 89/391/EEC Statutory Requirements: Health & Safety at Work Act 1974; Consumer Protection Act 1987; Environmental Protection Regulations 1991. Codes of Practice: Waste Management Duty of Care. Guidance Notes: Occupational skin disease guidance, exposure limits, and safe handling publications by HMSO/HSE.  

Other Information

The data applies only to the stated applications. Use outside of recommended applications may pose risks not described here. If supplying to third parties, ensure all users have this information. Employers must inform employees of hazards and precautions.

Product and Company Identification

(Page 1 may be used as an emergency safety sheet) Trade name: Low Halogen PVC Compound 135300 Chemical abstract no.: 9002-86-2 Chemical family: Polyvinyl Chloride with additives NIOSH no.: KU9625000 Chemical name: Polyvinyl chloride Synonyms: PVC Compound

Composition

UN no.: Not clas Hazardous components: Polyvinyl Chloride, Antimony Trioxide R Phrases: R37

Hazards Identification

Hard Grade PVC Compound 135300 is a pelletised granule and is either natural or black in colour. The compound has been designed for use as a low halogen PVC compound on Power Cables and conforms to SABS 1411 Part 2. The compound is very stable in its natural form and the normal precautionary measures should be taken when any contact is made with the material or in case of a fire. Eye effects: Fumes generated during processing may cause irritation. Health effects – skin: None, but avoid prolonged contact. Health effects – ingestion: Harmful as compounds contain lead stabilisers and antimony trioxide. Health effects – inhalation: Fumes generated during processing of PVC compound may cause irritation. Carcinogenicity: Not known. Mutagenicity: Not known. Neurotoxicity: Not known.

First Aid Measures

Product in eye: Flush eyes with clean water. Medical attention may be necessary if irritation persists. Product on skin: Wash with soap and water. For hot product, flush the affected area with cold water to dissipate heat. Do not remove material from the skin. Get prompt medical attention. Product ingested: Wash out mouth and give plenty of water to drink. Seek medical advice. Product inhaled: Remove from exposure to fresh air. Seek medical advice.

Fire Fighting Measures

Extinguishing media: CO2, Dry Chemical, Fog or Regular Foam may be used. Special hazards: The product is nonflammable and nonexplosive under normal conditions of use. When forced to burn, the major gaseous products are carbon monoxide, carbon dioxide, hydrogen chloride and water. Flame retardant additives ensure that the minimum quantity of hydrogen chloride is released. Protective clothing: An approved positive pressure self-contained apparatus must be worn.

Accidental Release Measures

Personal precautions: Pellets may cause slippage on hard surfaces. Environmental precautions: No data is available on the adverse effects of this product on the environment. Small spills: Sweep up and discard in waste containers (recycle if possible). Large spills: May be disposed of by landfill as per local regulations.

Handling and Storage

Suitable material: Keep stainless steel container tightly closed in a well ventilated place. Handling/storage precautions: Avoid contact with skin and eyes. Keep away from heat and sources of ignition.

Exposure Controls/Personal Protection

Engineering control measures: Ventilation requirements – local exhaust. Personal protection – respiratory: Use approved dust respirators. Personal protection – hand: Minimise contact with product. Wear gloves. Personal protection – eye: Wear safety glasses with side shields, goggles or a face shield for protection against dust. Personal protection – skin: Minimise contact with product. Wear gloves and/or suitable long sleeved clothing. Other protection:

Physical and Chemical Properties

Appearance: Pellets or Granules Odour: Faint soap like pH: Not applicable Boiling point: Not applicable Melting point: > 150ºC Flash point: > 450ºC Flammability: N/A Vapour pressure: N/A Density: 1.4 – 1.6 Solubility – water: Insoluble Solubility – solvent: Miscible in Cyclohexanone, Tetrahydofuran

Stability and Reactivity

Conditions to avoid: Polyvinyl chloride is stable under normal conditions. Incompatible materials: Polyvinyl chloride is incompatible with strong oxidising agents like sulphuric acid (>90%) and nitric acid (>50%). Strong inorganic acids will attack the polymer at temperatures > 60ºC. Halogens like bromine and fluorine attack Polyvinyl chloride at room temperature and can result in violent reactions. Hazardous decomposition products: Thermal decomposition can result in the release of toxic vapours of hydrogen chloride, carbon monoxide and carbon dioxide.

Toxicological Information

Acute toxicity: High concentrations of dust may irritate the upper respiratory tract. Vapour released during hot processing may cause respiratory irritation. Skin and eye contact: Repeated skin contact can cause irritation and abrasion. Direct eye contact can range from irritation to abrasion. Chronic toxicity: Chronic inhalation of dusts can cause pulmonary damage, blood effects and abnormal liver function. Carcinogenicity: Polyvinyl chloride is a questionable carcinogen with experimental tumorigenic data. Mutagenicity: Not known Neurotoxicity: Not known Reproductive hazards: Not known

Ecological Information

Aquatic toxicity – fish: Unlikely to be hazardous to aquatic life. Aquatic toxicity – daphnia: Unlikely to be hazardous. Aquatic toxicity – algae: Unlikely to be hazardous. Biodegradability: PVC shows no evidence for biodegradability in water or soil. Bio-accumulation: The product has no potential for bioaccumulation. Mobility: The product has no mobility in soil and can be substantially removed from effluent water in biological treatment processes.

Disposal Considerations

Disposal methods: Disposal should be in accordance with local, regional or national legislation. Disposal of packaging: N/A

Transport Information

PVC compounds are not listed as hazardous chemical substances and hence is not classified as dangerous for transport.

Product and Company Identification

(Page 1 may be used as an emergency safety sheet) Trade name: XLPE Chemical abstract no.: 009002-88-4 Chemical family: Crosslinked polyethylene, LLDPE, MDPE, HDPE, PP fillers NIOSH no.: None Chemical name: Polyethylene Homopolymer Hazchem code: None Synonyms: Polyethylene UN no.: None

Composition

Hazardous components: None EEC classification: –

Hazards Identification

Flammability: The product burns, but is not classified as flammable. Environmental hazard: Not considered dangerous to the environment. Health effects: The product is not classified as hazardous.

First Aid Measures

Product in eye: Wash with water. Product on skin: Wash with water. Product ingested: Do not induce vomiting. Obtain medical help. Product inhaled: Remove from exposure.

Fire Fighting Measures

Extinguishing media: Carbon dioxide, dry chemical powder or foam. Special hazards: Dense smoke; principal toxicant is carbon monoxide. Protective clothing: None.

Accidental Release Measures

Personal precautions: Spilt product presents a significant slip hazard. Environmental precautions: Prevent materials entering drain sewers.

Handling and Storage

Suitable material: Do not eat, drink or smoke whilst using this product. To avoid the possibility of skin disorders, repeated or prolonged contact with the product should be avoided. Maintain high personal hygiene. Handling/storage precautions: Store out of direct sunlight.

Exposure Controls/Personal Protection

Engineering control measures: Ventilation requirements – local exhaust. Personal protection – respiratory: Use approved dust respirators. Personal protection – hand: Minimise contact with product. Wear gloves. Personal protection – eye: Wear safety glasses. Personal protection – skin: Minimise contact with product. Wear gloves and/or suitable long sleeved clothing.

Physical and Chemical Properties

Appearance: Shiny plastic. Colour: Any colour ranging from black to white. pH: N/A. Boiling point: – Melting point: 110–140°C typical. Flash point: >300°C typical. Flammability: None. Autoflammability: None. Explosive properties: None. Oxidizing properties: Not applicable. Vapour pressure: None. Density: 0.9–1.0 g/cm³. Solubility – water: Insoluble.

Stability and Reactivity

Stability: Stable thermoplastic. Conditions to avoid: Excessive heat. Hazardous decomposition products: Hydrocarbons.

Toxicological Information

Acute toxicity: None. Skin and eye contact: Irritation causing discomfort. Chronic toxicity: Not known. Carcinogenicity: Not known. Mutagenicity: Not known. Neurotoxicity: Not known. Reproductive hazards: Not known.

Ecological Information

Aquatic toxicity – fish: Unlikely to be hazardous to aquatic life. Aquatic toxicity – daphnia: Unlikely to be hazardous. Aquatic toxicity – algae: Unlikely to be hazardous. Bio-accumulation: The product has no potential for bioaccumulation. Mobility: The product has no mobility in soil and can be substantially removed from effluent water in biological treatment processes.

Disposal Considerations

Disposal methods: Disposal should be in accordance with local, regional or national legislation. Disposal of packaging: N/A.

Transport Information

XLPE compounds are not listed as hazardous chemical substances and hence are not classified as dangerous for transport.

Product and Company Identification

(Page 1 may be used as an emergency safety sheet) Trade name: Zerotox Compound 145500 / 145501 Chemical abstract no.: 9002-86-2 Chemical family: Ethylene copolymers, aluminium or magnesium hydroxide, additives NIOSH no.: – Chemical name: Ethylene copolymers Synonyms: Non Halogenated Flame Retardant Compounds UN no.: Not classified as hazardous for transport

Composition

Hazardous components: None R Phrases: None S Phrases: None

Hazards Identification

Zerotox Compound 145500 / 145501 is a pelletised granule and is either natural or black in colour. The compound is designed as a No Halogen, Low Smoke, Fire Retardant compound for Power Cables and conforms to SABS 1411 Part 5. It is very stable in its natural form and normal precautionary measures should be taken during handling or in case of fire. Eye effects: Fumes generated during processing may cause irritation. Health effects – skin: None, but avoid prolonged contact. Health effects – ingestion: Not known. Health effects – inhalation: Not known. Carcinogenicity: Not known. Mutagenicity: Not known. Neurotoxicity: Not known.

First Aid Measures

Product in eye: Flush eyes with clean water. Medical attention may be necessary if irritation persists. Product on skin: Wash with soap and water. For hot product, flush with cold water. Do not remove material from skin. Seek medical attention. Product ingested: Wash mouth and give plenty of water. Seek medical advice. Product inhaled: Remove from exposure to fresh air. Seek medical advice.

Fire Fighting Measures

Extinguishing media: Water, CO₂, Dry Chemical, Fog or Regular Foam. Special hazards: Nonflammable under normal conditions. When forced to burn, may release carbon monoxide, carbon dioxide, hydrogen chloride and water.

Accidental Release Measures

Personal precautions: Pellets may cause slippage on hard surfaces. Environmental precautions: No data available on adverse environmental effects. Small spills: Sweep up and discard in waste containers (recycle if possible). Large spills: Dispose of by landfill as per local regulations.

Handling and Storage

Suitable material: Store in stainless steel container tightly closed in a well-ventilated area. Handling/storage precautions: Avoid contact with skin and eyes. Keep away from heat and ignition sources.

Exposure Controls/Personal Protection

Engineering control measures: Local exhaust ventilation. Personal protection – respiratory: Use approved dust respirators. Personal protection – hand: Minimise contact. Wear gloves. Personal protection – eye: Wear safety glasses with side shields, goggles or face shield. Personal protection – skin: Wear gloves and/or long sleeved clothing.

Physical and Chemical Properties

Appearance: Pellets or Granules Odour: Slight hydrocarbon-like pH: Not applicable Boiling point: Not applicable Melting point: > 150ºC Flash point: > 350ºC Flammability: N/A Vapour pressure: N/A Density: 1.4 – 1.6 Solubility – water: Insoluble Solubility – solvent: –

Stability and Reactivity

Hazardous reactions: None

Toxicological Information

Acute toxicity: High dust concentrations may irritate the respiratory tract. Vapours during hot processing may cause irritation. Skin and eye contact: Repeated contact may cause irritation or abrasion. Chronic toxicity: Chronic inhalation of dusts may cause pulmonary damage, blood effects and abnormal liver function. Mutagenicity: Not known. Neurotoxicity: Not known. Reproductive hazards: Not known.

Ecological Information

Aquatic toxicity – fish: Unlikely to be hazardous. Aquatic toxicity – daphnia: Unlikely to be hazardous. Aquatic toxicity – algae: Unlikely to be hazardous. Biodegradability: No evidence for biodegradability in water or soil. Bio-accumulation: No potential for bioaccumulation. Mobility: No mobility in soil; removable in biological water treatment.

Disposal Considerations

Disposal methods: Dispose in accordance with local, regional, or national legislation. Disposal of packaging: N/A.

Transport Information

Zerotox compounds are not listed as hazardous chemical substances and are not classified as dangerous for transport.

Regulatory Information

Risk phrases: None Safety phrases: None National legislation: –